Kane was in an excellent position in the box during the first half of Bayern's Champions League clash away to Aston Villa.
However, he was livid as his team-mate ignored him and wasted the opportunity.
The incident came just days after Kane was criticised by German newspaper BILD for his performance in Bayern's 1-1 draw with Bayer Leverkusen.
Kane was accused of 'hanging around alone up front' against Leverkusen, while it was also noted that he didn't have a shot on target.
Harry Kane was fuming after his Bayern Munich team-mate failed to pass to him
In the game against Aston Villa, Serge Gnabry had the option to play in either Kane or Michael Olise.
However, Gnabry went for goal himself and his effort lacked conviction as it went well off target.
Kane is hoping that this will finally be the season in which his wait for a trophy will come to an end.
Bayern are currently top of the Bundesliga table, having taken 13 points from their first five games of the campaign.
They will return to league action on Sunday with an away game against Eintracht Frankfurt, who are second.